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https://hdl.handle.net/11499/10903
Title: | Synthesis and characterization of new homo and heteronuclear schiff base copper(II) complexes | Authors: | Topal, Tufan Karapınar, Emin |
Keywords: | Heteronuclear Nickel Schiff base Trinuclear |
Publisher: | Turkish Chemical Society | Abstract: | This article describes the synthesis of isonitrosomethyl-p-tolyl ketone [HL] as the starting compound and then we prepared the new oxime ligand from the reactions of the amine materials with 1,2-diaminobenzene [H2L1]. (1E, 2E, 1'E, 2'E)-3,3'-bis [(4-tolyl ketone)-(1,2 phenylene diimine)]. Acetaldehyde dioxime ligand was used to synthesize the metal complexes. The complexes were elucidated by FT-IR, elemental analysis, magnetic moment measurements, molar conductivity, mass spectra, and TGA studies. The free ligand was also described with its13C and1H-NMR spectra. For complexes using spectroscopic and stoichiometric data of the complexes showed that metal:ligand ratio of mononuclear copper(II) complex was found to be 1:1 while this ratio was 2:1 in homo-and heterodinuclear copper(II) complex and 3:2 in the trinuclear copper(II) complex. All these data show us that the proposed structure is consistent with the obtained data. © 2018, Turkish Chemical Society. All rights reserved. | URI: | https://hdl.handle.net/11499/10903 https://doi.org/10.18596/jotcsa.324878 |
ISSN: | 2149-0120 |
Appears in Collections: | Fen-Edebiyat Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection TR Dizin İndeksli Yayınlar Koleksiyonu / TR Dizin Indexed Publications Collection |
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Synthesis and characterization.pdf | 495.61 kB | Adobe PDF | View/Open |
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