Please use this identifier to cite or link to this item:
https://hdl.handle.net/11499/10984
Title: | Phenylethanolamine A (PEA) imprinted polymer on carbon nitride nanotubes/graphene quantum dots/core-shell nanoparticle composite for electrochemical PEA detection in Urine sample | Authors: | Yola, M.L. Atar, Necip |
Keywords: | Body fluids Carbon nitride Chemical detection Core shell nanoparticles Electrochemical impedance spectroscopy Energy dispersive X ray analysis Glass membrane electrodes Gold compounds Nanocomposites Nanocrystals Nanotubes Nitrides Ruthenium compounds Scanning electron microscopy Semiconductor quantum dots Spectrum analysis Transmission electron microscopy X ray diffraction analysis X ray photoelectron spectroscopy Yarn 2-aminoethanethiol Carbon nitride nanotubes Energy dispersive x-ray analysis (EDX) Functionalized graphene Glassy carbon electrodes Hydrothermal treatments Molecular imprinted polymer (MIP) Voltammetric sensor Cyclic voltammetry |
Publisher: | Electrochemical Society Inc. | Abstract: | Phenylethanolamine A (PEA) is used illegally and deposited in animal tissues. Due to the reason, it causes acute poisoning and symptoms of muscular tremors, nervousness. In present article, Ru@Au core-shell nanoparticles (Ru@Au NPs) involved in carbon nitride nanotubes (C3N4 NTs) functionalized graphene quantum dots (GQDs) nanocomposite based molecular imprinted polymer (MIP) was formed for PEA recognition. Firstly, C3N4 NTs@GQDs nanocomposite was prepared by means of hydrothermal treatment. Secondly, this nanocomposite was functionalized with 2-aminoethanethiol (AET) via the affinity of gold-sulfur for binding Ru@Au NPs. After that, PEA imprinted voltammetric sensor was prepared in presence of 100.0 mM phenol as monomer containing 25.0 mM PEA by cyclic voltammetry (CV). All nanomaterials’ formation and properties were highlighted with scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), energy dispersive X-ray analysis (EDX), raman spectroscopy, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). 1.0 × 10-12 - 1.0 × 10-9 M and 2.0 × 10-13 M were founded as the linearity range and the detection limit (LOD). Finally, PEA imprinted glassy carbon electrode (GCE) was used for urine sample analysis in presence of the other competitor agents such as clenbuterol (CLE), ractopamine (RAC) and salbutamol (SAL). In addition, the stability and repeatability of prepared sensor was investigated. © 2018 The Electrochemical Society. | URI: | https://hdl.handle.net/11499/10984 https://doi.org/10.1149/2.0651802jes |
ISSN: | 0013-4651 |
Appears in Collections: | Mühendislik Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
Show full item record
CORE Recommender
SCOPUSTM
Citations
78
checked on Mar 29, 2025
WEB OF SCIENCETM
Citations
72
checked on Apr 1, 2025
Page view(s)
116
checked on Mar 4, 2025
Google ScholarTM
Check
Altmetric
Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.