Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/1491
Title: Periferal konumda oksa-aza grubu taşıyan metalli ftalosiyanin sentezi ve karakterizasyonu
Other Titles: The synthesis and characterization of metallophthalocyanines containing oxa-aza moiety in the peripheral position
Authors: Altunbaş, Ayşenur Kübra
Advisors: Yaşar Gök
Keywords: Ftalosiyanin
Periferal
Makrosiklik Bileşikler
Taç Eterler
Makrosiklizasyon
Phthalocyanine
Macrocyclic Compounds
Macrocyclization
Crown Ether
Publisher: Pamukkale Üniversitesi Fen Bilimleri Enstitüsü
Abstract: Bu çalışmada ilk olarak 1,8 bis-[2-(2-hidroksi-etoksi) amino]-antrakinon bileşiğine tosilleme işlemi yapılmıştır. 1,8 bis-[2-(2-tosiloksietoksi) amino]-antrakinon, 3,4- dihidroksi ftalonitril bileşiği ile reaksiyona sokularak 5,28-dioksa- 4,5,10,11,12,14,15,22,23,25,26,27-dodekahidro-4aH-4,6-metantribenzo [e,n,q][1,4,7,10,13,19]- tetraoksadiazasiklohenicosin -18,19- dikarbonitril bileşiği elde edilmiştir. Son olarak bu bileşiğin Kobalt Ftalosiyanini sentezlenmiştir. Elde edilen yeni maddelerin yapıları, 1H-NMR, 13C-NMR, IR, UV-vis. ve kütle spektroskopik verileri ve elemental analiz değerleri kullanarak aydınlatılmıştır.
In this study, firstly it was tosylationed. 1,8 bis-[2-(2-hidroxy-ethoxy) amino]- anthraquinone. 5,28-dioxo-4,5,10,11,12,14,15,22,23,25,26,27-dodecahydro-4aH-4,6- methanotribenzo-[e,n,q][1,4,7,10,13,19]-tetraoxadiazacyclohenicosine-18,19- dicarbonitrile compound was synthesized reaction of between 1,8 bis-[2-(2-tosiloxy-ethoxy) amino]-anthraquinone, 3,4-dihidroxy phthalonitrile. Finally, Cobalt phthalocyanine was synthesized. The structure of novel compounds have been investigated the combination of elemental analysis, IR, 1H and 13C-NMR, MS and UV-vis Data.
URI: https://hdl.handle.net/11499/1491
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