Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/1798
Title: Fosfor-1,1-ditiyolato bileşikleri ve bazı geçiş metal komplekslerinin sentezi
Other Titles: Synthesis of phosphor-1,1-dithiolate compounds and of their some transition metal complexes
Authors: Öcal, Şeyda
Advisors: Mehmet Karakuş
Keywords: Ditiyofosfonat
Ditiyofosfonik Asit
Ferrosenil Ditiyofosfonat
Cu(II), Pd(II) , Ag(I), Co(II) Metal Kompleksleri
Dithiophosphonate
Dithiophosphonic Acids
Ferrocenyl Dithiophosphonate
Ferrocene
Complexes of Cu(II), Pd(II) , Ag(I)
Abstract: Bu çalışmada Ferrosenil ditiyodifosfetan disülfür ile hidroksi bileşikleri (1,2:5,6-Di-O-izopropliden-alfa-D-glukofuranoz, 1,2:3,4-Di-O-izopropiliden-D-galaktopiranoz, 10-Hidroksibenzo[h]kinolin, 1-Ferrosenilethanol) ile etkileştirilmesi sonucu yeni O-ditiyofosfonatlar sentezlendi. O-ditiyofosfonik asitler ile trietilaminin muamele edilmesi sonucu trietilamonyum O-ditiyofosfonat tuzları halinde izole edildi. Bu tuzlar Cu(NO3)2, Pd(OAc)2, AgNO3, Co(CH3COO)2.4H2O, I2 ile kloroform, asetonitril ortamlarındaki reaksiyonları sonucu Pd(II) , Cu(II), Ag(I), Co(II) kompleksleri sentezlendi. Sentezlenen bileşiklerin yapıları elementel analiz, IR, 1H-, 31P-, 13C-NMR spektroskopisi ve kütle spektroskopisi ile karakterize edildi.
In this work, O-dithiophosphonates were synthesized by the reaction of Ferrocenyldithiadiphosphetane disulfide and hydroxy compounds, such as ROH(1,2:5,6-Di-O-isopropyliden-alpha-D-glucofuranose, 1,2:3,4-Di-O-isopropyliden-D-galactopyranose, 1-Ferrocenylethanol, 10-Hydroxybenzo[h]quinoline,) in toluene. The reaction of O-dithiophosponic with triethyl amine gave rise to triethyl ammonium O-dithiophosphonates. Cu(II), Pd(II), Ag(I), Co(II) -dithiophosphonate complexes were synthesized by the reaction of the corresponding metal salts and triethyl ammonium dithiophosphonates. All compounds were characterized by spectroscopically (IR, 1H-, 31P-, 13C-NMR) and also mass spectra.
URI: https://hdl.handle.net/11499/1798
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