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https://hdl.handle.net/11499/18378| Title: | Zwitterionic ferrocenyldithiophosphonates: the molecular structure of [FcP(S)S(OCH2CH2NH2Me)] [Fc = Fe(eta(5)-C5H4)(eta(5)-C5H5)] | Authors: | Karakus, M Lonnecke, P Hey-Hawkins, E |
Keywords: | zwitterionic ferrocenyldithiophosphonates; molecular structures | Publisher: | PERGAMON-ELSEVIER SCIENCE LTD | Abstract: | Ferrocenyldithiodiphosphetane [FcPS(mu-S)](2) [Fc = Fe(eta(5)-C5H4)(eta(5)-C5H5)] reacts with the aminoethanol derivatives HOCH2CH2NHMe and HOCH2CH2NEt2 to give the first structurally characterised examples of zwitterionic (O-ethylammonium)ferrocenyldithiophosphonates, [FcP(S)S((OCH2CH2NHRR2)-R-1)] (R-1 = H, R-2 = Me (1); R-1 = R-2 = Et (2)). 1 and 2 were characterised by elemental analyses, IR, NMR spectroscopy (H-1, C-13 (for 2) and P-31) and mass spectrometry. A crystal structure determination was carried out on 1. (C) 2004 Elsevier Ltd. All rights reserved. | URI: | https://hdl.handle.net/11499/18378 https://doi.org/10.1016/j.poly.2004.07.003 |
ISSN: | 0277-5387 |
| Appears in Collections: | Fen-Edebiyat Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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