Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/31905
Title: Synthesis and electropolymerization of a multifunctional naphthalimide clicked carbazole derivative
Authors: Çoban, Fatma
Ayrancı, Rukiye
Ak, Metin
Keywords: carbazole; 1; 8-naphthalimide; click chemistry; semiconducting polymer;
electrochemistry
Publisher: WILEY
Abstract: In this study, a multifunctional 'clicked' naphthalimide carbazole derivative (CNaP) was synthesized via Huisgen 1,3-dipolar cycloaddition reaction. Combining carbazole as an electroactive group with naphthalimide as a fluorescence group via click chemistry imparts multifunctional properties to this unique structure. CNaP was characterized via Fourier transform IR, C-13 and H-1 NMR spectroscopy as well as fluorescence and electrochemical measurements. The electrochemical polymerization of the CNaP monomer was carried out in acetonitrile/boron trifluoride diethyl etherate (2:1) (v/v) by the cyclic voltammetry technique. The resulting polycarbazole-derived conductive polymer was characterized via optical and electrochemical measurements. PCNaP displayed multi-electrochromism behaviour with good optical contrast (41% at 693 nm) and switching time (1.92 s at 693 nm). These results demonstrate that the new 'clicked' fluorescent, polycarbazole-derived conductive polymer can be used in various applications such as electrochemical/optical sensors and electrochromic and fluorescence imaging devices. (c) 2019 Society of Chemical Industry
URI: https://hdl.handle.net/11499/31905
https://doi.org/10.1002/pi.5942
ISSN: 0959-8103
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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