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https://hdl.handle.net/11499/3744
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ak, Metin | - |
dc.contributor.author | Toppare, Levent | - |
dc.date.accessioned | 2019-07-07T17:33:00Z | |
dc.date.available | 2019-07-07T17:33:00Z | |
dc.date.issued | 2009-04-15 | - |
dc.identifier.issn | 0254-0584 | - |
dc.identifier.uri | https://hdl.handle.net/11499/3744 | - |
dc.description.abstract | Star-shaped thiophene and pyrrole functionalized monomers namely 2,4,6-tris(4-(1H-pyrrol-1- yl)phenoxy)-1,3,5-triazine (TriaPy) and 2,4,6-tris(4-(1H-pyrrol-1-yl)phenoxy)-1,3,5-triazine (TriaTh) were synthesized from 2,4,6-trichloro-1,3,5-triazine, thiophen-3-ylmethanol and 4-(1H-pyrrol-1- yl)phenol. Electrochemical copolymerization of monomers with thiophene and pyrrole was achieved in tetrabutylammonium tetrafluoroborate/acetonitrile (TBAFB/AN). Resulting copolymers were characterized by Fourier transform infrared (FTIR) spectrometer, cyclic voltammetry (CV) and conductivity measurements. Spectroelectrochemical analysis reflected that copolymer films have low max for –* electronic transitions accompanied with a rather high band gap compared to polythiophene and polypyrrole. Switching abilities of copolymer films were evaluated by a kinetic study via measuring the transmittance (%T) at the maximum contrast. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier B.V. | en_US |
dc.relation.ispartof | Materials Chemistry and Physics | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Synthesis | en_US |
dc.subject | Electrochemistry | en_US |
dc.subject | Conducting polymers | en_US |
dc.subject | Spectroscopic analysis | en_US |
dc.subject | Electrochromic materials | en_US |
dc.subject | Electrochromic devices | en_US |
dc.subject | s-Triazines | en_US |
dc.subject | Spectroelectrochemistry | en_US |
dc.subject | Star-shaped polymers | en_US |
dc.subject | Copolymerization | en_US |
dc.subject | Cyclic voltammetry | en_US |
dc.subject | Fourier transform infrared spectroscopy | en_US |
dc.subject | Band gaps | en_US |
dc.subject | Conductivity measurements | en_US |
dc.subject | Copolymer films | en_US |
dc.subject | Electrochemical copolymerizations | en_US |
dc.subject | Electronic transitions | en_US |
dc.subject | Fourier transform infrared spectrometers | en_US |
dc.subject | Functionalized monomers | en_US |
dc.title | Synthesis of star-shaped pyrrole and thiophene functionalized monomers and optoelectrochemical properties of corresponding copolymers | en_US |
dc.type | Article | en_US |
dc.identifier.volume | 114 | en_US |
dc.identifier.issue | 2-3 | en_US |
dc.identifier.startpage | 789 | en_US |
dc.identifier.endpage | 794 | en_US |
dc.authorid | 0000-0002-0198-4617 | - |
dc.authorid | 0000-0002-0000-4613 | - |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.scopus | 2-s2.0-58849137012 | en_US |
dc.identifier.wos | WOS:000263833500052 | en_US |
dc.identifier.scopusquality | Q1 | - |
dc.owner | Pamukkale University | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.openairetype | Article | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
item.grantfulltext | open | - |
crisitem.author.dept | 17.01. Chemistry | - |
Appears in Collections: | Fen-Edebiyat Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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File | Description | Size | Format | |
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21 1.pdf | manuscript_abstract | 83.71 kB | Adobe PDF | ![]() View/Open |
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