Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/3903
Title: Blend or copolymer? Spectroelectrochemical evidence of copolymerization and blending of two electrochromic monomers
Authors: Ak, Metin
Çetişli, Halil
Toppare, Levent
Keywords: 3 ,4-ethylenedioxythiophene
Blends
Conducting polymers
Spectroscopic analysis
Ultraviolet spectroscopy
Electrochemistry
Electrochromic materials
Electrochromic properties
Electrochromics
Functionalized monomers
Spectral differences
Spectral properties
Spectroscopic analysis
Spectroelectrochemistry
Synthesis
Copolymers
Copolymerization
Chronoamperometry
Publisher: Springer Nature
Abstract: A dipyrromethane functionalized monomer, 5-(4-tert-butylphenyl) dipyrromethane (DP), was synthesized to examine the spectral differences of its copolymer and blend with 3,4-ethylenedioxythiophene. Electrochemical polymerization, copolymerization, and blending of DP were achieved in LiClO 4/Acetonitrile. Spectral and electrochromic properties of products were investigated. Spectral properties of copolymer and blend revealed great differences from each other and also from their corresponding homopolymers. Effect of monomer feed ratio on the spectral properties of copolymer was also investigated.
URI: https://hdl.handle.net/11499/3903
https://doi.org/10.1007/s00396-012-2787-7
ISSN: 0303-402X
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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