Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/3931
Title: An eco-friendly method to enhance optical and electrical properties of conducting polymers by means of carboxymethyl cellulose
Authors: Ak, Metin
Soğancı, Tuğba
Keywords: Conducting polymers
Green synthesis
Cellulose
Complexation
Composite films
Composite materials
Dispersions
Electrochemistry
Electrochromic materials
Spectroscopic analysis
Cyclic voltammetry
Electrodes
Electropolymerization
Environmental protection
Mechanical properties
Monomers
Spectroelectrochemistry
Carboxymethyl cellulose
Conductive composites
Optical and electrical properties
Mechanical properties
Polymerization potential
Spectroelectrochemical investigations
Surface morphology analysis
Thienylpyrroles
2,5-di(2-thienyl)pyrrole
Publisher: Springer Nature
Abstract: In this work, an eco-friendly method is proposed for the electro-synthesis of conductive polymers with superior optical and electrical properties by means of CMC in aqueous media. For this purpose, an aqueous dispersion of a water-insoluble monomer namely 4-amino-N-[2,5-di(thiophen-2-yl)-1H-pyrrol-1-yl]benzamide (TPB) has been prepared by attaching it to CMC via hydrogen bonds and the conductive composite film (PTPB–CMC) has been obtained by electropolymerization. The TPB monomer has been chosen to interact with the CMC via hydrogen bonds which ensures to obtain dispersion with the CMC and also increase the compatibility of its polymer in the composite structure. As a result of the electrochemical, spectroelectrochemical investigation and surface morphology analyses of the obtained conductive polymer, it has been found that anionic CMC makes improvements in the electrical, optical and mechanical properties of the polymer by making the plasticizing effect and acting as a dopant. Furthermore, in the presence of nanocarbon materials on electrode surface, it has been determined that the polymerization potential is reduced and more stable and long-lasting polymeric films which are crucial for technological applications have been obtained.
URI: https://hdl.handle.net/11499/3931
ISSN: 0969-0239
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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