Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/3952
Title: Syntheses of electroactive layers based on functionalized anthracene for electrochromic applications
Authors: Yıldırım, Ayşegül
Tarkuç, Simge
Ak, Metin
Toppare, Levent
Keywords: Synthesis
Electrochemistry
Conducting polymers
Spectroscopic analysis
Electrochromic materials
Electrochemical copolymerization
Cyclic voltammetry
Chronoamperometry
Anthracene
Publisher: Elsevier B.V.
Abstract: A new monomer (DTAT) was synthesized via linking 3,4-ethylenedioxythiophene (EDOT) on anthracene. The polymer, P(DTAT) was electrosynthesized by anodic oxidation of the corresponding monomer in 0.1 M LiClO4 acetonitrile (ACN) solution. The optical properties, the absorption spectra and the kinetics, were examined. Spectroelectrochemical analysis showed that P(DTAT) has an electronic band gap (due to ?-?* transition) of 1.57 eV at 776 nm. Copolymers of DTAT with EDOT were prepared in ACN/LiClO4 (0.1 M) solvent-electrolyte couple by varying applied potential. The incorporation of an EDOT into the full conjugated backbone, DTAT, affects its optical behavior resulting in different colors; a claret red neutral state, gray and red intermediate states and a blue oxidized state.
URI: https://hdl.handle.net/11499/3952
ISSN: 0013-4686
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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