Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/3965
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dc.contributor.authorAk, Metin-
dc.contributor.authorGacal, Burcin-
dc.contributor.authorKiskan, Baris-
dc.contributor.authorYagci, Yusuf-
dc.contributor.authorToppare, Levent-
dc.date.accessioned2019-07-11T12:33:47Z
dc.date.available2019-07-11T12:33:47Z
dc.date.issued2008-04-
dc.identifier.issn0032-3861-
dc.identifier.urihttps://hdl.handle.net/11499/3965-
dc.description.abstractA new monomer, octa(thiophenephenyl)silsesquioxane (OThiophenePS) was synthesized via click chemistry. The chemical structure of OThiophenePS was characterized by nuclear magnetic resonance (1H NMR) and Fourier transform infrared (FT-IR) spectroscopies. Electrochemical polymerization of pyrrole with OThiophenePS was performed resulting in polypyrrole-attached, polyhedral oligomeric silsesquioxane (OPS-PPy). The spectroelectrochemical studies show that the electrochromic properties of (OPS-PPy) are superior to those of polypyrrole (PPy). This great improvement can be attributed to the more accessible doping sites and the facile ion movement during the redox switching brought by the loose packing of the PPy chains.en_US
dc.language.isoenen_US
dc.publisherElsevier B.V.en_US
dc.relation.ispartofPolymeren_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectSynthesisen_US
dc.subjectElectrochemistryen_US
dc.subjectConducting polymersen_US
dc.subjectSpectroscopic analysisen_US
dc.subjectNuclear magnetic resonanceen_US
dc.subjectClick chemistryen_US
dc.subjectPolaronsen_US
dc.subjectPolypyrrolesen_US
dc.subjectPolyhedral oligomeric silsesquioxaneen_US
dc.titleEnhancing electrochromic properties of polypyrrole by silsesquioxane nanocagesen_US
dc.typeArticleen_US
dc.identifier.volume49en_US
dc.identifier.issue9en_US
dc.identifier.startpage2202en_US
dc.identifier.endpage2210en_US
dc.authorid0000-0001-6244-6786-
dc.authorid0000-0002-0198-4617-
dc.authorid0000-0001-9476-2054-
dc.authorid0000-0002-0000-4613-
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.scopus2-s2.0-42049111427en_US
dc.identifier.wosWOS:000255923200003en_US
dc.identifier.scopusqualityQ1-
dc.ownerPamukkale University-
item.grantfulltextopen-
item.fulltextWith Fulltext-
item.cerifentitytypePublications-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.languageiso639-1en-
item.openairetypeArticle-
crisitem.author.dept17.01. Chemistry-
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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