In situ preparation of rhodium/N-heterocyclic carbene complexes and use for addition of arylboronic acids to aldehydes

Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/4384

Title:	In situ preparation of rhodium/N-heterocyclic carbene complexes and use for addition of arylboronic acids to aldehydes
Authors:	Kılınçarslan, Rafet Yigit, M. Özdemir, I. Çetinkaya, E. Çetinkaya, B.
Keywords:	alcohol derivative aldehyde derivative alkyl group benzene derivative boronic acid derivative carbene heterocyclic compound imidazolidine derivative polycyclic aromatic hydrocarbon derivative potassium derivative rhodium addition reaction article catalysis complex formation infrared spectroscopy proton nuclear magnetic resonance quantum yield reaction analysis stereospecificity synthesis
Publisher:	HeteroCorporation
Abstract:	(Chemical Equation Presented) The in situ prepared three component system [RhCl(COD)]2/imidazolidinium salts (2, 4) and KOBut catalyses the addition of phenylboronic acid to sterically hindered aldehydes affording the corresponding arylated secondary alcohols in good yields. Four novel 1,3-dialkylimidazolidinium (2-4) salts as NHC precursors were synthesized from N,N'-dialkylethylenediamine.
URI:	https://hdl.handle.net/11499/4384 https://doi.org/10.1002/jhet.5570440111
ISSN:	0022-152X
Appears in Collections:	Fen-Edebiyat Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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