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https://hdl.handle.net/11499/4389
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Bıyıklıoğlu, Z. | - |
dc.contributor.author | Ertem, B. | - |
dc.contributor.author | Karslıoğlu, S. | - |
dc.contributor.author | Gök, Yaşar. | - |
dc.date.accessioned | 2019-08-16T11:33:50Z | |
dc.date.available | 2019-08-16T11:33:50Z | |
dc.date.issued | 2007 | - |
dc.identifier.issn | 0340-4285 | - |
dc.identifier.uri | https://hdl.handle.net/11499/4389 | - |
dc.identifier.uri | https://doi.org/10.1007/s11243-007-0215-5 | - |
dc.description.abstract | The novel (E,E)-dioxime,7,8-bis(hydroxyimino)-1,14-bis(monoaza[8]crown-6)- benzo[f]-4,11-dioxa-1,14-diazadecane[7,8-g]quinoxaline (H 2 L), has been synthesized by the reaction of 6,7-diamino-1,12-bis(monoaza[18]crown-6) benzo[f]-4,9-dioxa-1,12-diazadecane (4) which has been prepared by the reduction of 6,7-dinitro-1,12-bis(mono-aza[18]crown-6)benzo[f]-4,9-dioxa-1,12-diazdecane (3) and cyanogendi-N-oxide. Mononuclear Ni II and Cu II complexes of H 2 L have a metal:ligand ratio of 1:2 and the ligand coordinates through two hydroxyimino nitrogen atoms, as do most of the (E,E)-dioximes. The hydrogen-bridged Ni II complex was converted into its BF 2 + capped anologue by the reaction with BF 3 • Et 2 O. The reaction of the Cu II complex with 2,2'-dipyridyl as an end-cap ligand gave the homotrinuclear complex. Structures for the ligand and its complexes are proposed in accordance with elemental analysis, magnetic susceptibility measurements, 1 H, 13 C-n.m.r, IR and MS spectral data. © 2007 Springer. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Springer Netherlands | en_US |
dc.relation.ispartof | Transition Metal Chemistry | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Amino acids | en_US |
dc.subject | Complexation | en_US |
dc.subject | Ligands | en_US |
dc.subject | Nitrogen compounds | en_US |
dc.subject | Reduction | en_US |
dc.subject | Synthesis (chemical) | en_US |
dc.subject | Dioxime | en_US |
dc.subject | Hydroxyimino nitrogen atoms | en_US |
dc.subject | Ligand ratio | en_US |
dc.subject | Polynuclear metal complexes | en_US |
dc.subject | Metal complexes | en_US |
dc.title | Synthesis and characterization of novel (E,E)-dioxime and its mono- and polynuclear metal complexes containing azacrown moieties | en_US |
dc.type | Article | en_US |
dc.identifier.volume | 32 | en_US |
dc.identifier.issue | 5 | en_US |
dc.identifier.startpage | 591 | |
dc.identifier.startpage | 591 | en_US |
dc.identifier.endpage | 596 | en_US |
dc.authorid | 0000-0001-8679-2149 | - |
dc.identifier.doi | 10.1007/s11243-007-0215-5 | - |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.scopus | 2-s2.0-34547222683 | en_US |
dc.identifier.wos | WOS:000248116900007 | en_US |
dc.identifier.scopusquality | Q2 | - |
dc.owner | Pamukkale University | - |
item.languageiso639-1 | en | - |
item.openairetype | Article | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.fulltext | No Fulltext | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
Appears in Collections: | Fen-Edebiyat Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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