Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/46594
Title: Determination of cobalt and copper in water, plant, and soil samples by magnetite nanoparticle-based solid-phase microextraction (SPME) coupled with microsample injection system-flame atomic absorption spectrometry (MIS-FAAS)
Authors: Sadiqov, Elvin
Sodan, Nilgun Elyas
Siyal, Ali N.
Elci, Aydan
Elci, Latif
Keywords: Fe3O4 NPs
solid-phase microextraction (SPME)
cobalt
copper
microsample injection system-flame atomic absorption spectrometry (MIS-FAAS)
Iron-Oxide Nanoparticles
Trace Amounts
Extraction
Preconcentration
Ions
Removal
Polythiophene
Nanocomposite
Sorbent
Nickel
Publisher: Taylor & Francis Inc
Abstract: A magnetic solid-phase microextraction (SPME) procedure was optimized using Fe3O4 nanoparticles (NPs) to preconcentrate and determine cobalt and copper in real samples using microsample injection system-flame atomic absorption spectrometry (MIS-FAAS). Recoveries over 95% for Co(II) and 80% for Cu(II) from 90 mL of sample buffered to pH 4.0 were obtained using 50 mg Fe3O4 NPs as the adsorbent and 0.5 mL of 0.5 mol L-1 HNO3 as the eluent. The extraction time was 10 min. The preconcentration factors for Co(II) and Cu(II) were 180. The detection limits for Co(II) and Cu(II) were 1.2 and 0.9 mu g L-1, respectively. The relative uncertainties and relative standard deviations were lower than 5.3% and 2.4%, respectively. The developed method was verified by analyzing TMDW-500 drinking water, NIST 1573a Tomato leaves, and NCS DC 78302 Tibet soil as standard reference materials. The spiking experiments provided recoveries exceeding 95%. The method was applied to determine cobalt and copper in water, soil, tea infusion, and vegetable samples.
URI: https://doi.org/10.1080/10739149.2021.2002891
https://hdl.handle.net/11499/46594
ISSN: 1073-9149
1525-6030
Appears in Collections:Diğer Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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