Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/4766
Title: Synthesis and characterization of a new (E,E)-dioxime and its homonuclear complexes
Authors: Karapınar, Emin
Keywords: BF2+ - capped complex
Crown compounds
Glyoximes
Transition metal complexes
Abstract: N'-(4'-Benzo[15-crown-5]naphthylaminoglyoxime (H2L) and its sodium chloride complex (H2L·NaCl) have been prepared from 2-naphthylchloroglyoxime, 4'-aminobenzo[15-crown-5] and sodium bicarbonate or sodium bicarbonate and sodium chloride. Nickel(II), cobalt(II) and copper(II) complexes of H2L and H2L·NaCl have a metal-ligand ratio of 1:2 and the ligand coordinates through the two N atoms, as do most of the vic-dioximes. The BF 2 + -capped Ni(II), Co(III) and mononuclear complexes of thevic-dioxime were prepared. The macrocyclic ligands and their transition metal complexes have been characterized on the basis of IR, 1H NMR spectroscopy and elemental analyses data. © Springer 2005.
URI: https://hdl.handle.net/11499/4766
https://doi.org/10.1007/s10847-005-2548-z
ISSN: 0923-0750
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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