Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/5032
Title: Paramagnetic octahedral p-methoxyphenyldithiophosphonato nickel(II) complexes: Crystal structures of [Ni{S2P(OR)(p-CH3O-C 6H4)-?S,S'}2(L-?N) 2] (R = Et, 2,4-tBu2C6H3, L = 3-acetylpyridine)
Authors: Karakuş, Mehmet
Lönnecke, P.
Hey-Hawkins, E.
Keywords: Dithiophosphonates
Octahedral paramagnetic nickel(II) complexes
nickel
nickel complex
pyridine derivative
article
chemical reaction
crystal
crystal structure
infrared spectroscopy
magnetism
mass spectrometry
ultraviolet spectroscopy
Abstract: The square-planar NiII complexes [Ni{S2P(OR)(p- CH3O-C6H4)-?S,S'}2] react with 3-acetylpyridine to give green crystals of the paramagnetic octahedral complexes [Ni{S2P(OR)(p-CH3O-C 6H4)-?S,S'}2(L-?N) 2] [R = Et (1), iPr (2), 2,4-tBu 2C6H3 (3); L = 3-acetylpyridine]. Complexes 1-3 were characterized by IR, MS, and UV-vis spectroscopy, and crystal structures were determined for 1 and 3. The magnetic moments for 1-3 are 3.04-3.15 B.M.
URI: https://hdl.handle.net/11499/5032
https://doi.org/10.1002/zaac.200400053
ISSN: 0044-2313
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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