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https://hdl.handle.net/11499/58017
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DC Field | Value | Language |
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dc.contributor.advisor | Kılınçarslan, Rafet | en_US |
dc.contributor.author | Tuncer, Hayriye | en_US |
dc.date.accessioned | 2024-10-14T13:27:11Z | - |
dc.date.available | 2024-10-14T13:27:11Z | - |
dc.date.issued | 2024 | - |
dc.identifier.uri | https://hdl.handle.net/11499/58017 | - |
dc.description | Bu tez çalışması Pamukkale Üniversitesi tarafından 2021FEBE034 nolu proje ile desteklenmiştir. | en_US |
dc.description.abstract | Bu çalışmada, karben öncüsü N-sübstitüye benzotiyazolyum tuzları hazırlanarak, öncülerin metal tuzlarıyla tepkimesinden, literatürde yeni Pd(II)-NSHC ve Ru(II)-NSHC kompleksleri sentezlenmiştir. Bileşikler, NMR, FT-IR, UV-Vis, HR-ESI-MS, EDX-SEM, DTA-TG, elemental analiz ve tek-kristal X-Ray difraksiyon kristalografisi yöntemleriyle karakterize edilmiştir. Ru(II) komplekslerinin transfer hidrojenasyon ve Pd(II) komplekslerinin C-C bağ kenetlenmesindeki katalitik aktiviteleri araştırılmıştır. Seçilen komplekslerin antikanser, antimikrobiyal, antifungal ve elektropolimerizasyon özellikleri incelenmiştir. | en_US |
dc.description.abstract | In this study, carbene precursor N-substituted benzothiazolium salts were prepared and new Pd(II)-NSHC and Ru(II)-NSHC complexes in the literature were synthesized by reacting the precursors with metal salts. The compounds were characterized by NMR, FT-IR, UV-Vis, HR-ESI- MS, EDX-SEM, DTA-TG, elemental analysis and single-crystal X-Ray diffraction crystallographic methods. The catalytic activities of Ru(II) complexes in transfer hydrogenation and Pd(II) complexes in C-C bond coupling were examined. The anticancer, antimicrobial, antifungal and electropolymerization properties of selected complexes were investigated. | en_US |
dc.language.iso | tr | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Benzotiyazol | en_US |
dc.subject | N,S-heterosiklik karben | en_US |
dc.subject | NSHC | en_US |
dc.subject | Ru(II)-NSHC | en_US |
dc.subject | Pd(II)-NSHC | en_US |
dc.subject | elektropolimerizasyon | en_US |
dc.subject | Suzuki-Miyaura | en_US |
dc.subject | transfer hidrojenasyon | en_US |
dc.subject | antikanser | en_US |
dc.subject | antimikrobiyal | en_US |
dc.subject | antifungal | en_US |
dc.title | N-heterosiklik karben (NHC) komplekslerinin (LnM-NHC) sentezi, biyolojik ve katalitik aktivitelerinin incelenmesi | en_US |
dc.title.alternative | Synthesis of N-heterocyclic carbene (NHC) complexes (LnM-NHC) and investigation of their biological and catalytic activities | en_US |
dc.type | Doctoral Thesis | en_US |
dc.department | PAÜ, Enstitüler, Fen Bilimleri Enstitüsü | en_US |
dc.authorid | 0000-0002-4261-5965 | en_US |
dc.relation.publicationcategory | Tez | en_US |
dc.identifier.yoktezid | 899940 | en_US |
dc.contributor.affiliation | Pamukkale Üniversitesi | en_US |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | open | - |
item.languageiso639-1 | tr | - |
item.openairetype | Doctoral Thesis | - |
item.fulltext | With Fulltext | - |
item.cerifentitytype | Publications | - |
crisitem.author.dept | 17.01. Chemistry | - |
Appears in Collections: | Tez Koleksiyonu |
Files in This Item:
File | Description | Size | Format | |
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RF no10377199.pdf | 16.16 MB | Adobe PDF | View/Open |
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