Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/58017
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dc.contributor.advisorKılınçarslan, Rafeten_US
dc.contributor.authorTuncer, Hayriyeen_US
dc.date.accessioned2024-10-14T13:27:11Z-
dc.date.available2024-10-14T13:27:11Z-
dc.date.issued2024-
dc.identifier.urihttps://hdl.handle.net/11499/58017-
dc.descriptionBu tez çalışması Pamukkale Üniversitesi tarafından 2021FEBE034 nolu proje ile desteklenmiştir.en_US
dc.description.abstractBu çalışmada, karben öncüsü N-sübstitüye benzotiyazolyum tuzları hazırlanarak, öncülerin metal tuzlarıyla tepkimesinden, literatürde yeni Pd(II)-NSHC ve Ru(II)-NSHC kompleksleri sentezlenmiştir. Bileşikler, NMR, FT-IR, UV-Vis, HR-ESI-MS, EDX-SEM, DTA-TG, elemental analiz ve tek-kristal X-Ray difraksiyon kristalografisi yöntemleriyle karakterize edilmiştir. Ru(II) komplekslerinin transfer hidrojenasyon ve Pd(II) komplekslerinin C-C bağ kenetlenmesindeki katalitik aktiviteleri araştırılmıştır. Seçilen komplekslerin antikanser, antimikrobiyal, antifungal ve elektropolimerizasyon özellikleri incelenmiştir.en_US
dc.description.abstractIn this study, carbene precursor N-substituted benzothiazolium salts were prepared and new Pd(II)-NSHC and Ru(II)-NSHC complexes in the literature were synthesized by reacting the precursors with metal salts. The compounds were characterized by NMR, FT-IR, UV-Vis, HR-ESI- MS, EDX-SEM, DTA-TG, elemental analysis and single-crystal X-Ray diffraction crystallographic methods. The catalytic activities of Ru(II) complexes in transfer hydrogenation and Pd(II) complexes in C-C bond coupling were examined. The anticancer, antimicrobial, antifungal and electropolymerization properties of selected complexes were investigated.en_US
dc.language.isotren_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectBenzotiyazolen_US
dc.subjectN,S-heterosiklik karbenen_US
dc.subjectNSHCen_US
dc.subjectRu(II)-NSHCen_US
dc.subjectPd(II)-NSHCen_US
dc.subjectelektropolimerizasyonen_US
dc.subjectSuzuki-Miyauraen_US
dc.subjecttransfer hidrojenasyonen_US
dc.subjectantikanseren_US
dc.subjectantimikrobiyalen_US
dc.subjectantifungalen_US
dc.titleN-heterosiklik karben (NHC) komplekslerinin (LnM-NHC) sentezi, biyolojik ve katalitik aktivitelerinin incelenmesien_US
dc.title.alternativeSynthesis of N-heterocyclic carbene (NHC) complexes (LnM-NHC) and investigation of their biological and catalytic activitiesen_US
dc.typeDoctoral Thesisen_US
dc.departmentPAÜ, Enstitüler, Fen Bilimleri Enstitüsüen_US
dc.authorid0000-0002-4261-5965en_US
dc.relation.publicationcategoryTezen_US
dc.identifier.yoktezid899940en_US
dc.contributor.affiliationPamukkale Üniversitesien_US
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextopen-
item.languageiso639-1tr-
item.openairetypeDoctoral Thesis-
item.fulltextWith Fulltext-
item.cerifentitytypePublications-
crisitem.author.dept17.01. Chemistry-
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