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https://hdl.handle.net/11499/58444
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kilincarslan, Rafet | - |
dc.contributor.author | Menderes, Melek | - |
dc.contributor.author | Tuncer, Hayriye | - |
dc.contributor.author | Ozdemir, Sedef | - |
dc.contributor.author | Ozdemir, Namik | - |
dc.contributor.author | Cetinkaya, Bekir | - |
dc.date.accessioned | 2024-12-21T16:37:18Z | - |
dc.date.available | 2024-12-21T16:37:18Z | - |
dc.date.issued | 2025 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.issn | 1099-0682 | - |
dc.identifier.uri | https://doi.org/10.1002/ejic.202400621 | - |
dc.description | Kılınçarslan, Rafet/0000-0001-6982-9536; Tuncer, Hayriye/0000-0002-4261-5965; Ozdemir, Namik/0000-0003-3371-9874 | en_US |
dc.description.abstract | Thiamine analogues with 3-methyl and 4-(2-hydroxyethyl) substituents on the backbone of thiazole ring, were used to synthesize monodentate Ru(II)-thiazolylidene complexes in a single step via transmetalation under mild conditions. These novel complexes catalyze the conversion of ketones and aldehydes to alcohols by transfer hydrogenation in a 5 : 2 HCO2H/NEt3 buffer in water. However, their efficiency was found to be much lower than the thiamine-derived bidentate Ru(II) complexes, which strongly indicates that the 'N-H' plays a crucial role in the reaction. | en_US |
dc.description.sponsorship | Pamukkale University Scientific Research Projects Commission; Scientific and Technological Research Application and Research Center of Sinop University; [2023FEBE011] | en_US |
dc.description.sponsorship | Financial support for this work was provided by the Pamukkale University Scientific Research Projects Commission (Project No: 2023FEBE011). The authors acknowledge to Scientific and Technological Research Application and Research Center of Sinop University for the X-ray data collections. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Wiley-v C H verlag Gmbh | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Thiamine | en_US |
dc.subject | Thiazol-2-Ylidene | en_US |
dc.subject | Ru(Ii)-Nshc | en_US |
dc.subject | N,S-Heterocyclic Carbene | en_US |
dc.subject | Transfer Hydrogenation | en_US |
dc.title | Synthesis and Characterization of Ru(ii)-Nshc Catalysts Bearing Thiamine Analogs in Water-Solvent Transfer Hydrogenation Catalysis | en_US |
dc.type | Article | en_US |
dc.identifier.volume | 28 | en_US |
dc.identifier.issue | 2 | en_US |
dc.department | Pamukkale University | en_US |
dc.authorid | KILINCARSLAN, RAFET/0000-0001-6982-9536 | - |
dc.authorid | TUNCER, HAYRIYE/0000-0002-4261-5965 | - |
dc.authorid | Ozdemir, Namik/0000-0003-3371-9874 | - |
dc.identifier.doi | 10.1002/ejic.202400621 | - |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorwosid | KILINCARSLAN, RAFET/D-8120-2015 | - |
dc.authorwosid | TUNCER, HAYRIYE/AAX-6639-2021 | - |
dc.authorwosid | Ozdemir, Namik/J-6434-2015 | - |
dc.identifier.scopus | 2-s2.0-85208816428 | en_US |
dc.identifier.scopus | 2-s2.0-85208816428 | - |
dc.identifier.wos | WOS:001397174800003 | - |
dc.institutionauthor | … | - |
dc.identifier.scopusquality | Q2 | - |
dc.description.woscitationindex | Science Citation Index Expanded | - |
dc.identifier.wosquality | Q2 | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.cerifentitytype | Publications | - |
item.fulltext | No Fulltext | - |
item.grantfulltext | none | - |
item.openairetype | Article | - |
item.languageiso639-1 | en | - |
crisitem.author.dept | 17.01. Chemistry | - |
crisitem.author.dept | 17.01. Chemistry | - |
Appears in Collections: | Fen Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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