Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/5923
Title: Remediation of fungicide residues on fresh produce by use of gaseous ozone
Authors: Walse, S.S.
Karaca, Hakan
Keywords: Cyprodinil
Fenhexamids
Flowthrough
Fresh produce
Gaseous ozone
Glass surfaces
Grape berry
Heterogeneous rate constant
Kinetics and mechanism
Liquid chromatography-Mass spectrometry
Maximum residue levels
Model surface
Ozone fumigation
Ozonolysis
Product analysis
Pseudo-first-order
Pyrimethanil
Agricultural chemicals
Fruits
Fungicides
Gas chromatography
Glass
Liquid chromatography
Mass spectrometry
Ozone
Rate constants
Analysis of variance (ANOVA)
boscalid
cyprodinil
fenhexamid
fungicide
iprodione
ozone
pesticide residue
pyrimethanil
unclassified drug
air quality
atmospheric pollution
factor analysis
gas chromatography
glass
liquid chromatography
mass spectrometry
reaction kinetics
variance analysis
vine
analysis of variance
article
bioremediation
concentration (parameters)
controlled study
crop
fumigation
grape
nonhuman
oxidation
ozonolysis
California
Environmental Remediation
Fumigation
Fungicides, Industrial
Gas Chromatography-Mass Spectrometry
Kinetics
Molecular Weight
Oxidants
Pesticide Residues
Pyrimidines
Vitis
Vitaceae
Abstract: Ozone fumigation was explored as a means for degrading organic fungicide residues on fresh produce. Fungicides sorbed onto model abiotic glass surfaces or onto grape berries were fumigated separately in a flow-through chamber. Gaseous ozone at a constant concentration of 150 ± 10 ppmv (µL•L -1) selectively oxidized fungicides sorbed to model surfaces. Over 140 min, boscalid and iprodione levels did not change significantly based on a single-factor analysis of variance (ANOVA) at the 95% level of confidence (p = 0.05); however, pseudo-first-order losses resulted in observable rate constants of ozonolysis, k ozonolysis (min -1), of 0.0233 ± 0.0029 (t 1/2 ? 29.7 min), 0.0168 ± 0.0028 (t 1/2 ? 41.3 min), and 0.0127 ± 0.0010 (t 1/2 ? 54.6 min) for fenhexamid, cyprodinil, and pyrimethanil, respectively. The relative degradation of fungicides on berries at gaseous ozone concentrations of 900 ± 12 ppmv (µL•L -1) over 2 h was similar to that on glass; decreases in residue concentration were observed for only fenhexamid (~64%), cyprodinil (~38%), and pyrimethanil (~35%) with corresponding k ozonolysis (min -1) of 0.0085 ± 0.0021 (t 1/2 ? 81.5 min), 0.0039 ± 0.0008 (t 1/2 ? 177.7 min), and 0.0036 ± 0.0007 (t 1/2 ? 192.5 min). Heterogeneous rate constants of gaseous ozone reacting with a sorbed fungicide, k O3(M -1•min -1), were calculated for both surfaces and indicate losses proceed ~15-fold slower on grapes. The kinetics and mechanism of fungicide removal, supported by gas chromatography- and liquid chromatography-mass spectrometry product analyses, is discussed in the context of facilitating compliance with maximum residue level (MRL) tolerances for fresh produce. © 2011 American Chemical Society.
URI: https://hdl.handle.net/11499/5923
https://doi.org/10.1021/es2006868
ISSN: 0013-936X
Appears in Collections:Mühendislik Fakültesi Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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