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https://hdl.handle.net/11499/5923
Title: | Remediation of fungicide residues on fresh produce by use of gaseous ozone | Authors: | Walse, S.S. Karaca, Hakan |
Keywords: | Cyprodinil Fenhexamids Flowthrough Fresh produce Gaseous ozone Glass surfaces Grape berry Heterogeneous rate constant Kinetics and mechanism Liquid chromatography-Mass spectrometry Maximum residue levels Model surface Ozone fumigation Ozonolysis Product analysis Pseudo-first-order Pyrimethanil Agricultural chemicals Fruits Fungicides Gas chromatography Glass Liquid chromatography Mass spectrometry Ozone Rate constants Analysis of variance (ANOVA) boscalid cyprodinil fenhexamid fungicide iprodione ozone pesticide residue pyrimethanil unclassified drug air quality atmospheric pollution factor analysis gas chromatography glass liquid chromatography mass spectrometry reaction kinetics variance analysis vine analysis of variance article bioremediation concentration (parameters) controlled study crop fumigation grape nonhuman oxidation ozonolysis California Environmental Remediation Fumigation Fungicides, Industrial Gas Chromatography-Mass Spectrometry Kinetics Molecular Weight Oxidants Pesticide Residues Pyrimidines Vitis Vitaceae |
Abstract: | Ozone fumigation was explored as a means for degrading organic fungicide residues on fresh produce. Fungicides sorbed onto model abiotic glass surfaces or onto grape berries were fumigated separately in a flow-through chamber. Gaseous ozone at a constant concentration of 150 ± 10 ppmv (µL•L -1) selectively oxidized fungicides sorbed to model surfaces. Over 140 min, boscalid and iprodione levels did not change significantly based on a single-factor analysis of variance (ANOVA) at the 95% level of confidence (p = 0.05); however, pseudo-first-order losses resulted in observable rate constants of ozonolysis, k ozonolysis (min -1), of 0.0233 ± 0.0029 (t 1/2 ? 29.7 min), 0.0168 ± 0.0028 (t 1/2 ? 41.3 min), and 0.0127 ± 0.0010 (t 1/2 ? 54.6 min) for fenhexamid, cyprodinil, and pyrimethanil, respectively. The relative degradation of fungicides on berries at gaseous ozone concentrations of 900 ± 12 ppmv (µL•L -1) over 2 h was similar to that on glass; decreases in residue concentration were observed for only fenhexamid (~64%), cyprodinil (~38%), and pyrimethanil (~35%) with corresponding k ozonolysis (min -1) of 0.0085 ± 0.0021 (t 1/2 ? 81.5 min), 0.0039 ± 0.0008 (t 1/2 ? 177.7 min), and 0.0036 ± 0.0007 (t 1/2 ? 192.5 min). Heterogeneous rate constants of gaseous ozone reacting with a sorbed fungicide, k O3(M -1•min -1), were calculated for both surfaces and indicate losses proceed ~15-fold slower on grapes. The kinetics and mechanism of fungicide removal, supported by gas chromatography- and liquid chromatography-mass spectrometry product analyses, is discussed in the context of facilitating compliance with maximum residue level (MRL) tolerances for fresh produce. © 2011 American Chemical Society. | URI: | https://hdl.handle.net/11499/5923 https://doi.org/10.1021/es2006868 |
ISSN: | 0013-936X |
Appears in Collections: | Mühendislik Fakültesi Koleksiyonu PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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