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https://hdl.handle.net/11499/5965
Title: | Chiral heterobimetallic gold(I) ferrocenyldithiophosphonato complexes | Authors: | Karakuş, Mehmet Lönnecke, P. Hildebrand, M. Hey-Hawkins, E. |
Keywords: | Chiral ferrocenyldithiophosphonates Dithiophosphonato gold(I) complexes Gold Metallocenes Molecular structures |
Abstract: | Chiral and non-chiral ferrocenyldithiophosphonates [tBuNH 3][Fe(?5-C5H5) {?5-C5H4P(OR)S2}] were prepared from [Fe(?5-C5H5){?5-C 5H4PS(µ-S)}]2 and the respective alcohol ROH [R = bornyl (1), myrtenyl (2), adamantyl (3)] and tBuNH2 as base. The reaction with [AuCl(tht)] (tht = tetrahydrothiophene) gave the corresponding chiral (1a, 2a) and non-chiral (3a) heterobimetallic dimeric gold(I) ferrocenyldithiophosphonato complexes [Au{Fe(?5-C 5H5)(?5-C5H4P(OR) (µ-S)2)}]2 [R = bornyl (1a), myrtenyl (2a), adamantyl (3a)]. Compounds 1-3 and 1a-3a were characterised spectroscopically (IR, 1H, 13C, 31P NMR) and by mass spectrometry, and the chiral heterobimetallic dimeric gold(I) ferrocenyldithiophosphonato complex 1a was also structurally characterised by X-ray crystallography. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | URI: | https://hdl.handle.net/11499/5965 https://doi.org/10.1002/zaac.201100004 |
ISSN: | 0044-2313 |
Appears in Collections: | Fen-Edebiyat Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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