Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/5965
Title: Chiral heterobimetallic gold(I) ferrocenyldithiophosphonato complexes
Authors: Karakuş, Mehmet
Lönnecke, P.
Hildebrand, M.
Hey-Hawkins, E.
Keywords: Chiral ferrocenyldithiophosphonates
Dithiophosphonato gold(I) complexes
Gold
Metallocenes
Molecular structures
Abstract: Chiral and non-chiral ferrocenyldithiophosphonates [tBuNH 3][Fe(?5-C5H5) {?5-C5H4P(OR)S2}] were prepared from [Fe(?5-C5H5){?5-C 5H4PS(µ-S)}]2 and the respective alcohol ROH [R = bornyl (1), myrtenyl (2), adamantyl (3)] and tBuNH2 as base. The reaction with [AuCl(tht)] (tht = tetrahydrothiophene) gave the corresponding chiral (1a, 2a) and non-chiral (3a) heterobimetallic dimeric gold(I) ferrocenyldithiophosphonato complexes [Au{Fe(?5-C 5H5)(?5-C5H4P(OR) (µ-S)2)}]2 [R = bornyl (1a), myrtenyl (2a), adamantyl (3a)]. Compounds 1-3 and 1a-3a were characterised spectroscopically (IR, 1H, 13C, 31P NMR) and by mass spectrometry, and the chiral heterobimetallic dimeric gold(I) ferrocenyldithiophosphonato complex 1a was also structurally characterised by X-ray crystallography. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
URI: https://hdl.handle.net/11499/5965
https://doi.org/10.1002/zaac.201100004
ISSN: 0044-2313
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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