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Title: | Determination of Triazine Herbicides and Metabolites by Solid Phase Extraction with HPLC Analysis | Authors: | Akdoğan, Abdullah Divrikli, Ümit Elçi, Latif |
Keywords: | Herbicide HPLC Metabolites Preconcentration SPE |
Abstract: | An efficient solid phase extractive preconcentration/separation method was developed for the trace determination of herbicides in aqueous samples using Amberlite XAD-4 resin as the adsorbent. The retained herbicides were eluted with methanol at a flow rate of 1.0 mL min-1 and determined by HPLC-DAD (wavelength of 220 nm) using water (pH:4.7, phosphoric acid) and methanol (ratio 35:65) as the mobile phase with a flow rate of 1.0 mL min-1. Quantitative recoveries of simazine, atrazine and its metabolities were achieved at optimized analysis conditions that included 0.75 g of resin; a pH of 3.0; an eluent volume of 3.0 mL; an eluent flow rate of 1.0 mL min-1; and a sample flow rate of 4.0 mL min-1. The limits of detection, preconcentration factor, and linear ranges for the herbicides were 0.084-0.121 µgL-1, 1000, and 0.5-20 mg L-1, respectively. The performance of the method was evaluated by analysis of spiked water samples. The recoveries of simazine, atrazine and their metabolities were found to be quantitative (99.6-104.8%) with RSDs of 2.2-4.8% and 2.8-4.7% for intra-day and inter-day precision, respectively. The proposed method was successfully applied for trace determination of studied analytes in waste water, apple juice, and red wine samples. © 2013 Copyright Taylor and Francis Group, LLC. | URI: | https://hdl.handle.net/11499/7956 https://doi.org/10.1080/00032719.2013.800542 |
ISSN: | 0003-2719 |
Appears in Collections: | Fen-Edebiyat Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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