Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/8114
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dc.contributor.authorŞahin, Çiğdem-
dc.contributor.authorVarlikli, C.-
dc.contributor.authorZafer, C.-
dc.contributor.authorShi, Q.-
dc.contributor.authorDouthwaite, R.E.-
dc.date.accessioned2019-08-16T12:35:37Z
dc.date.available2019-08-16T12:35:37Z
dc.date.issued2013-
dc.identifier.issn0095-8972-
dc.identifier.urihttps://hdl.handle.net/11499/8114-
dc.identifier.urihttps://doi.org/10.1080/00958972.2013.782486-
dc.description.abstractThe new heteroleptic ruthenium(II) complex containing a 1H-pyridin-(2E)-ylidene (PYE) ligand was synthesized and characterized using UV/Vis, FTIR, and NMR spectroscopies, mass spectrometry, elemental analysis, and cyclic voltammetry. The photovoltaic performance of the ruthenium complex as a charge transfer photosensitizer in nc-titanium dioxide based dye-sensitized solar cell was studied and compared with cis-bis(isothiocyanato)(2,2'-bipyridyl- 4,4'-dicarboxylato)(2,2'-bipyridyl-4,4'-di-nonyl)ruthenium(II) (Z907) under standard AM 1.5 sunlight. The complex CS90 gave a photocurrent density of 1.80mAcm-2, 400mV open-circuit potential, and 0.58 fill factor yielding an efficiency of 0.42% where the reference Z907 yielded an efficiency of 4.12%. The decrease in conversion efficiency observed for CS90 is attributed to a steric interaction between PYE and the TiO2 surface that prevents optimum binding and also restricts ligand dynamics that are associated with oxidation state changes. © 2013 Taylor & Francis.en_US
dc.language.isoenen_US
dc.relation.ispartofJournal of Coordination Chemistryen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject1H-Pyridin-(2E)-ylideneen_US
dc.subjectDye-sensitized solar cellsen_US
dc.subjectRuthenium(II) complexesen_US
dc.titleA new 1H-pyridin-(2E)-ylidene ruthenium complex as sensitizer for a dye-sensitized solar cellen_US
dc.typeArticleen_US
dc.identifier.volume66en_US
dc.identifier.issue8en_US
dc.identifier.startpage1384
dc.identifier.startpage1384en_US
dc.identifier.endpage1395en_US
dc.authorid0000-0002-9993-9637-
dc.identifier.doi10.1080/00958972.2013.782486-
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.scopus2-s2.0-84877947750en_US
dc.identifier.wosWOS:000320643100010en_US
dc.identifier.scopusqualityQ2-
dc.ownerPamukkale University-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.grantfulltextnone-
item.languageiso639-1en-
item.openairetypeArticle-
item.fulltextNo Fulltext-
item.cerifentitytypePublications-
crisitem.author.dept14.01. Surgical Medicine-
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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