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https://hdl.handle.net/11499/8114
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Şahin, Çiğdem | - |
dc.contributor.author | Varlikli, C. | - |
dc.contributor.author | Zafer, C. | - |
dc.contributor.author | Shi, Q. | - |
dc.contributor.author | Douthwaite, R.E. | - |
dc.date.accessioned | 2019-08-16T12:35:37Z | |
dc.date.available | 2019-08-16T12:35:37Z | |
dc.date.issued | 2013 | - |
dc.identifier.issn | 0095-8972 | - |
dc.identifier.uri | https://hdl.handle.net/11499/8114 | - |
dc.identifier.uri | https://doi.org/10.1080/00958972.2013.782486 | - |
dc.description.abstract | The new heteroleptic ruthenium(II) complex containing a 1H-pyridin-(2E)-ylidene (PYE) ligand was synthesized and characterized using UV/Vis, FTIR, and NMR spectroscopies, mass spectrometry, elemental analysis, and cyclic voltammetry. The photovoltaic performance of the ruthenium complex as a charge transfer photosensitizer in nc-titanium dioxide based dye-sensitized solar cell was studied and compared with cis-bis(isothiocyanato)(2,2'-bipyridyl- 4,4'-dicarboxylato)(2,2'-bipyridyl-4,4'-di-nonyl)ruthenium(II) (Z907) under standard AM 1.5 sunlight. The complex CS90 gave a photocurrent density of 1.80mAcm-2, 400mV open-circuit potential, and 0.58 fill factor yielding an efficiency of 0.42% where the reference Z907 yielded an efficiency of 4.12%. The decrease in conversion efficiency observed for CS90 is attributed to a steric interaction between PYE and the TiO2 surface that prevents optimum binding and also restricts ligand dynamics that are associated with oxidation state changes. © 2013 Taylor & Francis. | en_US |
dc.language.iso | en | en_US |
dc.relation.ispartof | Journal of Coordination Chemistry | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | 1H-Pyridin-(2E)-ylidene | en_US |
dc.subject | Dye-sensitized solar cells | en_US |
dc.subject | Ruthenium(II) complexes | en_US |
dc.title | A new 1H-pyridin-(2E)-ylidene ruthenium complex as sensitizer for a dye-sensitized solar cell | en_US |
dc.type | Article | en_US |
dc.identifier.volume | 66 | en_US |
dc.identifier.issue | 8 | en_US |
dc.identifier.startpage | 1384 | |
dc.identifier.startpage | 1384 | en_US |
dc.identifier.endpage | 1395 | en_US |
dc.authorid | 0000-0002-9993-9637 | - |
dc.identifier.doi | 10.1080/00958972.2013.782486 | - |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.identifier.scopus | 2-s2.0-84877947750 | en_US |
dc.identifier.wos | WOS:000320643100010 | en_US |
dc.identifier.scopusquality | Q2 | - |
dc.owner | Pamukkale University | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.grantfulltext | none | - |
item.languageiso639-1 | en | - |
item.openairetype | Article | - |
item.fulltext | No Fulltext | - |
item.cerifentitytype | Publications | - |
crisitem.author.dept | 14.01. Surgical Medicine | - |
Appears in Collections: | Fen-Edebiyat Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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