Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/8176
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dc.contributor.authorÖzcan, Yusuf-
dc.contributor.authorIde, S.-
dc.contributor.authorJeng, U.-
dc.contributor.authorBütün, V.-
dc.contributor.authorLai, Y.H.-
dc.contributor.authorSu, C.H.-
dc.date.accessioned2019-08-16T12:36:33Z
dc.date.available2019-08-16T12:36:33Z
dc.date.issued2013-
dc.identifier.issn0254-0584-
dc.identifier.urihttps://hdl.handle.net/11499/8176-
dc.identifier.urihttps://doi.org/10.1016/j.matchemphys.2012.12.019-
dc.description.abstractWe have studied the micellization behavior of tertiary amine methacrylate-based diblock copolymers, comprising the hydrophobic poly[2-(diethylamino)ethyl methacrylate] (PDEA) and hydrophilic/polyelectrolyte poly[2-(dimethylamino)ethyl methacrylate] (PDMA) blocks. Revealed by small-angle X-ray scattering (SAXS) and dynamics light scattering, micelle size of the PDMAm-b-PDEAn diblock copolymer in aqueous solution depends sensitively on the comonomer ratio n/m, molecular weight Mw, solution temperature, and solution pH values. Aggregation number is found to follow an empirical relation of N (n/m)1.6, disregarding the molecular mass. With n/m = 0.5, Mw ? 12,000, and pH = 7.6, the diblock copolymer forms spherical core-shell micelles at 23 °C, with a PDEA-core radius of 52, a PDMA-shell thickness of 27, and an aggregation number of 127. © 2013 Elsevier B.V. All rights reserved.en_US
dc.language.isoenen_US
dc.relation.ispartofMaterials Chemistry and Physicsen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectChemical synthesisen_US
dc.subjectLight scatteringen_US
dc.subjectPolymersen_US
dc.subjectSmall-angle scatteringen_US
dc.subject2-(dimethylamino)ethyl methacrylateen_US
dc.subjectAggregation numbersen_US
dc.subjectCo-monomeren_US
dc.subjectCore-shellen_US
dc.subjectEmpirical relationsen_US
dc.subjectEthyl methacrylatesen_US
dc.subjectMicelle sizeen_US
dc.subjectMicellization behavioren_US
dc.subjectSmall angle X-ray scatteringen_US
dc.subjectSolution pHen_US
dc.subjectSolution temperatureen_US
dc.subjectTertiary amineen_US
dc.subjectMicellesen_US
dc.subjectMicellizationen_US
dc.subjectOrganic compoundsen_US
dc.subjectX ray scatteringen_US
dc.subjectBlock copolymersen_US
dc.titleMicellization behavior of tertiary amine-methacrylate-based block copolymers characterized by small-angle X-ray scattering and dynamic light scatteringen_US
dc.typeArticleen_US
dc.identifier.volume138en_US
dc.identifier.issue2-3en_US
dc.identifier.startpage559
dc.identifier.startpage559en_US
dc.identifier.endpage564en_US
dc.authorid0000-0003-4355-5383-
dc.identifier.doi10.1016/j.matchemphys.2012.12.019-
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.identifier.scopus2-s2.0-84874524099en_US
dc.identifier.wosWOS:000316580000022en_US
dc.identifier.scopusqualityQ1-
dc.ownerPamukkale University-
item.grantfulltextnone-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.openairetypeArticle-
item.languageiso639-1en-
item.fulltextNo Fulltext-
crisitem.author.dept20.03. Biomedical Engineering-
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection
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