Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/10120
Title: The Extraction Ability and Sensitivity of Porphyrazine Derivatives Towards Some Transition Metal Cations
Authors: Kabay, Nilgün
Baygu, Yasemin
Ocak, Ümmühan
Gün, Serhat
Gök, Yaşar
Keywords: extraction
magnesium porphyrazine
metal-free porphyrazine
mixed donor macrocycle
transition metals
Chromium compounds
Cobalt compounds
Copper
Extraction
Lead
Lead compounds
Magnesium
Manganese
Mercury (metal)
Metal ions
Metals
Nickel
Positive ions
Solvent extraction
Spectrophotometry
Transition metals
Zinc
Zinc compounds
Cyclotetramerization
Extraction properties
Macrocycles
Metal cation
Porphyrazines
Spectral data
Spectro-photometric method
Transition metal cations
Cadmium compounds
Publisher: Taylor and Francis Inc.
Abstract: The synthesis of novel metal-free and magnesium porphyrazines, peripherally substituted with dithia-dioxa (S2O2) and tetrathia (S4) 14-membered macrocycles were performed by cyclotetramerization of (6Z)-1,3,4,9,10,12-hexahydro-2,5,8,11-benzo-dioxadithiacyclotetradecine-6,7-dicarbodinitrile (3) or (6Z)-1,3,4,9,10,12-hexahydro 2,5,8,11-benzotetrathiacyclotetradecine-6,7-dicarbodinitrile (5). The metal-free porphyrazines have been obtained by known route. The structure of compounds were characterized by elemental analysis and 1H, 13C NMR, IR, UV-vis, and MS spectral data. The solvent extraction properties of the synthesized compounds towards some metal cations, such as Ag(I), Hg(II), Cu(II), Mn(II), Cr(III), Ni(II), Pb(II), and Zn(II) have been investigated. The effect of Cu2+, Mn2+, Ni2+, Pb2+, Sr2+, Al3+, Zn2+, Ba2+, Cd2+, Co2+, Hg2+, and Ag+ ions on the absorption spectra of the compounds were investigated by means of spectrophotometric method. Magnesium porphyrazine with S2O2 (6) interacted within Hg2+ ion specifically of all the tested metal ions. © , Copyright © Taylor & Francis Group, LLC.
URI: https://hdl.handle.net/11499/10120
https://doi.org/10.1080/01496395.2014.978468
ISSN: 0149-6395
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Teknoloji Fakültesi Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

Show full item record



CORE Recommender

SCOPUSTM   
Citations

3
checked on Oct 13, 2024

WEB OF SCIENCETM
Citations

2
checked on Dec 11, 2024

Page view(s)

48
checked on Aug 24, 2024

Google ScholarTM

Check




Altmetric


Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.