Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/3766
Title: Ferrocenyl dithiophosphonate functionalized inorganic-organic hybrid conductive polymer with green color in neutral state
Authors: Koyundereli Çılgı, Gülbanu
Karakuş, Mehmet
Ak, Metin
Keywords: Boron trifluoride diethyl etherate
Conductive Polymers
Electrochemical techniques
Inorganic-organic hybrid
Metallopolymers
Spectroelectrochemical analysis
Spectroelectrochemical properties
Square-planar nickel
Electrochemistry
Electrochromic materials
Electrochromic devices
Green colored electrochromic
Metal complex
Publisher: Elsevier B.V.
Abstract: We report the synthesis and the characterization of the first electroactive ferrocenyl dithiophosphonate functionalized inorganic-organic hybrid conductive polymer. Electropolymerization was realized in boron trifluoride diethyl etherate (BFEE) with an applied potential of 1.5 V. Surface morphological, spectroelectrochemical, colorimetric and redox properties of polymer were investigated. Spectroelectrochemical and colorimetry studies have shown that ThFc has green color in neutral state. The reaction of the ferrocenyl dithiophosphonate and nickel(II) acetate gave rise to square-planar nickel(II)complex (ThFc-Ni). ThFc-Ni complex copolymerize with thiophene and spectroelectrochemical properties of copolymer were also investigated.
URI: https://hdl.handle.net/11499/3766
https://doi.org/10.1016/j.synthmet.2013.07.017
ISSN: 0379-6779
Appears in Collections:Fen-Edebiyat Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Teknoloji Fakültesi Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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