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https://hdl.handle.net/11499/3858
Title: | Comparative investigation of peripheral and nonperipheral zinc phthalocyanine-based polycarbazoles in terms of optical, electrical, and sensing properties | Authors: | Soğancı, Tuğba Baygu, Yasemin Kabay, Nilgün Gök, Yaşar Ak, Metin |
Keywords: | Nitrogen compounds Photodynamic therapy Zinc phthalocyanines Nonperipheral Polycarbazoles zinc(II) phthalocyanine Phthalocyanines Analytical optimizations Cyclotetramerization Electrical properties Phthalocyanine molecules Sensors Sensor platforms Glucose sensors Graphite electrodes Glucose concentration Glucose oxidase Optical contrast Optical properties |
Publisher: | American Chemical Society | Abstract: | In this study, nonperipherally alkyl-linked carbazole conjugated novel zinc(II) phthalocyanine was synthesized by cyclotetramerization reaction of 6-(9H-carbazol-9-yl)hexane-1-thiol and 3,6-bis(tosyloxy) phthalonitrile in a one-step reaction. Optical, electrical, and sensing properties of this super structured polycarbazole obtained by electropolymerization are compared with peripherally alkyl-linked polycarbazole-based zinc(II) phthalocyanine. It has been found that the attachment of alkyl-linked carbazoles to the phthalocyanine molecule in either peripheral or nonperipheral positions has a great effect on the optical and electrical properties and sensing ability of the resulting polycarbazole derivatives. P(n-ZnPc) has the highest electrochromic contrast (70.5%) among the derivatives of zinc(II) phthalocyanines in the literature. In addition to these, the sensor platform has been successfully established, and analytical optimizations have been carried out. When the sensors prepared with zinc(II) phthalocyanine are examined, it was specified that the n-ZnPc-co-TP/GOx was ranked first in the literature with high sensor response and stability. As a result, by changing of the peripheral and nonperipheral position of phthalocyanines, their physical properties can be tuned to meet the requirements of desired technological application. | URI: | https://hdl.handle.net/11499/3858 | ISSN: | 1944-8244 |
Appears in Collections: | Fen-Edebiyat Fakültesi Koleksiyonu PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection Teknoloji Fakültesi Koleksiyonu WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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