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https://hdl.handle.net/11499/47777
Title: | Novel Nonperipheral Octa-3 Substituted Metallo-Phthalocyanines: Synthesis, Characterization, and Investigation of Their Electrochemical, Photochemical and Computational Properties | Authors: | Kabay, Nilgun Baygu, Yasemin Metin, A. K. Kara, Izzet Kaya, Esra Nur Durmus, Mahmut GoK, Yasar |
Keywords: | Metallo-Phthalocyanines Cyclic Voltammetry Computational Chemistry Photodynamic Therapy Photochemical Properties |
Publisher: | Tubitak Scientific & Technological Research Council Turkey | Abstract: | The current study describes the synthesis, electrochemical, computational, and photochemical properties of octa (3-hydroxypropylthio) substituted cobalt (II) (4), copper (II) (5), nickel (II) (6) and zinc(II) (7) phthalocyanine derivatives. These novel compounds were characterized by elemental analysis, H-1, C-13 NMR, FT-IR, UV-Vis, and MS. The redox behaviors of these metallophthalocyanines were investigated by the cyclic voltammetric method. The optimized molecular structure and gauge-including atomic orbital (GIAO) H-1 and C-13 NMR chemical shift values of these phthalocyanines in the ground state had been calculated by using B3LYP/6-31G(d,p) basis set. The outcomes of the optimized molecular structure were given and compared with the experimental NMR values. The photochemical properties including photodegradation and singlet oxygen generation of zinc(II) phthalocyanine were studied in DMSO solution for the determination of its photosensitizer behaviors. | Description: | Kara, Izzet/0000-0002-9837-2819; Baygu Yildiz, Yasemin/0000-0003-3776-9633; Ak, Metin/0000-0002-0000-4613 | URI: | https://doi.org/10.3906/kim-2008-48 | ISSN: | 1300-0527 |
Appears in Collections: | PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection TR Dizin İndeksli Yayınlar Koleksiyonu / TR Dizin Indexed Publications Collection WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection |
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Novel nonperipheral octa-3-hydroxypropylthio substituted metallo-.pdf | 7.95 MB | Adobe PDF | View/Open |
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