Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/47777
Title: Novel nonperipheral octa-3-hydroxypropylthio substituted metallo-phthalocyanines: Synthesis, characterization, and investigation of their electrochemical, photochemical and computational properties
Authors: Kabay, Nilgün
Bayğu, Yasemin
Ak, Metin
Kara, İzzet
Kaya, Esra Nur
Durmuş, Mahmut
Gök,Yaşar
Keywords: Computational chemistry
Cyclic voltammetry
Metallo-phthalocyanines
Photochemical properties
Photodynamic therapy
Publisher: TUBITAK
Abstract: The current study describes the synthesis, electrochemical, computational, and photochemical properties of octa (3-hydroxypropylthio) substituted cobalt (II) (4), copper (II) (5), nickel (II) (6) and zinc(II) (7) phthalocyanine derivatives. These novel compounds were characterized by elemental analysis, 1H, 13C NMR, FT-IR, UV-Vis, and MS. The redox behaviors of these metallophthalocyanines were investigated by the cyclic voltammetric method. The optimized molecular structure and gauge-including atomic orbital (GIAO) 1H and 13C NMR chemical shift values of these phthalocyanines in the ground state had been calculated by using B3LYP/6-31G(d,p) basis set. The outcomes of the optimized molecular structure were given and compared with the experimental NMR values. The photochemical properties including photodegradation and singlet oxygen generation of zinc(II) phthalocyanine were studied in DMSO solution for the determination of its photosensitizer behaviors. © This work is licensed under a Creative Commons Attribution 4.0 International License.
URI: https://doi.org/10.3906/KIM-2008-48
https://search.trdizin.gov.tr/yayin/detay/525670
https://hdl.handle.net/11499/47777
ISSN: 1300-0527
Appears in Collections:Eğitim Fakültesi Koleksiyonu
Fen-Edebiyat Fakültesi Koleksiyonu
Mühendislik Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
Tavas Meslek Yüksekokulu Koleksiyonu
TR Dizin İndeksli Yayınlar Koleksiyonu / TR Dizin Indexed Publications Collection

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