Please use this identifier to cite or link to this item:
https://hdl.handle.net/11499/47777
Title: | Novel nonperipheral octa-3-hydroxypropylthio substituted metallo-phthalocyanines: Synthesis, characterization, and investigation of their electrochemical, photochemical and computational properties | Authors: | Kabay, Nilgün Bayğu, Yasemin Ak, Metin Kara, İzzet Kaya, Esra Nur Durmuş, Mahmut Gök,Yaşar |
Keywords: | Computational chemistry Cyclic voltammetry Metallo-phthalocyanines Photochemical properties Photodynamic therapy |
Publisher: | TUBITAK | Abstract: | The current study describes the synthesis, electrochemical, computational, and photochemical properties of octa (3-hydroxypropylthio) substituted cobalt (II) (4), copper (II) (5), nickel (II) (6) and zinc(II) (7) phthalocyanine derivatives. These novel compounds were characterized by elemental analysis, 1H, 13C NMR, FT-IR, UV-Vis, and MS. The redox behaviors of these metallophthalocyanines were investigated by the cyclic voltammetric method. The optimized molecular structure and gauge-including atomic orbital (GIAO) 1H and 13C NMR chemical shift values of these phthalocyanines in the ground state had been calculated by using B3LYP/6-31G(d,p) basis set. The outcomes of the optimized molecular structure were given and compared with the experimental NMR values. The photochemical properties including photodegradation and singlet oxygen generation of zinc(II) phthalocyanine were studied in DMSO solution for the determination of its photosensitizer behaviors. © This work is licensed under a Creative Commons Attribution 4.0 International License. | URI: | https://doi.org/10.3906/KIM-2008-48 https://search.trdizin.gov.tr/yayin/detay/525670 https://hdl.handle.net/11499/47777 |
ISSN: | 1300-0527 |
Appears in Collections: | Eğitim Fakültesi Koleksiyonu Fen-Edebiyat Fakültesi Koleksiyonu Mühendislik Fakültesi Koleksiyonu Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection Tavas Meslek Yüksekokulu Koleksiyonu TR Dizin İndeksli Yayınlar Koleksiyonu / TR Dizin Indexed Publications Collection |
Files in This Item:
File | Size | Format | |
---|---|---|---|
Novel nonperipheral octa-3-hydroxypropylthio substituted metallo-.pdf | 7.95 MB | Adobe PDF | View/Open |
CORE Recommender
SCOPUSTM
Citations
3
checked on Dec 7, 2024
Page view(s)
48
checked on Aug 24, 2024
Download(s)
12
checked on Aug 24, 2024
Google ScholarTM
Check
Altmetric
Items in GCRIS Repository are protected by copyright, with all rights reserved, unless otherwise indicated.