Please use this identifier to cite or link to this item: https://hdl.handle.net/11499/47777
Title: Novel Nonperipheral Octa-3 Substituted Metallo-Phthalocyanines: Synthesis, Characterization, and Investigation of Their Electrochemical, Photochemical and Computational Properties
Authors: Kabay, Nilgun
Baygu, Yasemin
Metin, A. K.
Kara, Izzet
Kaya, Esra Nur
Durmus, Mahmut
GoK, Yasar
Keywords: Metallo-Phthalocyanines
Cyclic Voltammetry
Computational Chemistry
Photodynamic Therapy
Photochemical Properties
Publisher: Tubitak Scientific & Technological Research Council Turkey
Abstract: The current study describes the synthesis, electrochemical, computational, and photochemical properties of octa (3-hydroxypropylthio) substituted cobalt (II) (4), copper (II) (5), nickel (II) (6) and zinc(II) (7) phthalocyanine derivatives. These novel compounds were characterized by elemental analysis, H-1, C-13 NMR, FT-IR, UV-Vis, and MS. The redox behaviors of these metallophthalocyanines were investigated by the cyclic voltammetric method. The optimized molecular structure and gauge-including atomic orbital (GIAO) H-1 and C-13 NMR chemical shift values of these phthalocyanines in the ground state had been calculated by using B3LYP/6-31G(d,p) basis set. The outcomes of the optimized molecular structure were given and compared with the experimental NMR values. The photochemical properties including photodegradation and singlet oxygen generation of zinc(II) phthalocyanine were studied in DMSO solution for the determination of its photosensitizer behaviors.
Description: Kara, Izzet/0000-0002-9837-2819; Baygu Yildiz, Yasemin/0000-0003-3776-9633; Ak, Metin/0000-0002-0000-4613
URI: https://doi.org/10.3906/kim-2008-48
ISSN: 1300-0527
Appears in Collections:PubMed İndeksli Yayınlar Koleksiyonu / PubMed Indexed Publications Collection
Scopus İndeksli Yayınlar Koleksiyonu / Scopus Indexed Publications Collection
TR Dizin İndeksli Yayınlar Koleksiyonu / TR Dizin Indexed Publications Collection
WoS İndeksli Yayınlar Koleksiyonu / WoS Indexed Publications Collection

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